A list of selected national libraries of the world is provided in the table.
| library | location | year founded1 | special collections, archives, papers |
|---|---|---|---|
| 1In present institutional form. | |||
| 2Originally founded in the 3rd century BCE. | |||
| 3Originally founded in 1753 as the British Museum Library. | |||
| 4Originally founded in 1832 as the Public Library. | |||
| Alexandrina Library | Alexandria, Egypt | 20022 | ancient manuscripts, Egyptian heritage |
| British Library | London | 19733 | Charles Dickens, George B. Shaw |
| Central National Library of Florence | Florence | 1861 | Reformation, Galileo Galilei |
| Central National Library of Rome | Rome | 1876 | Jesuit collections, Gabriele D'Annunzio |
| German National Library Frankfurt am Main | Germany | 2006 | bibliographies, exile literature (1933–45) |
| German National Library Leipzig | Germany | 2006 | socialism, Anne-Frank-Shoah-Bibliothek |
| The National Library of Israel | Jerusalem | 1892 | world Jewish history, Albert Einstein |
| Library and Archives Canada | Ottawa | 2004 | hockey, portraits of Canadians |
| Library of Congress | Washington, D.C. | 1800 | Americana, folk music, early motion pictures |
| National Agricultural Library | Beltsville, Md. | 1962 | research reports |
| National Diet Library | Tokyo | 1948 | Japanese culture, Allied occupation |
| National Library | Rio de Janeiro | 1810 | botany, Latin American music |
| National Library | Warsaw | 1928 | engravings, music |
| National Library of Australia | Canberra | 1960 | Asian and Pacific area |
| National Library of China | Beijing | 1909 | art, early communism |
| National Library of Education | Washington, D.C. | 1994 | research reports |
| National Library of France | Paris | 1461 | Denis Diderot, Jean-Paul Sartre |
| National Library of Greece | Athens | 18664 | incunabula |
| National Library of India | Kolkata (Calcutta) | 1903 | rare journals of vernacular languages |
| National Library of Ireland | Dublin | 1877 | biography, Gaelic manuscripts |
| National Library of Medicine | Bethesda, Md. | 1956 | history of medicine |
| National Library of Mexico | Mexico City | 1867 | Jesuit works, early Mexican printing |
| National Library of New Zealand | Wellington | 1965 | European exploration, missionary activity |
| National Library of Pakistan | Islamabad | 1993 | manuscripts, censuses |
| National Library of Portugal | Lisbon | 1796 | Luís de Camões, Desiderius Erasmus |
| National Library of Russia | St. Petersburg | 1795 | rare books, Russian history |
| National Library of Scotland | Edinburgh | 1925 | mountaineering, witchcraft |
| National Library of South Africa | Pretoria; Cape Town | 1999 | Africana, cookery |
| National Library of Spain | Madrid | 1836 | manuscripts, Miguel de Cervantes |
| National Library of Sweden | Stockholm | 1661 | Scandinavian cartography and manuscripts |
| National Library of Venezuela | Caracas | 1833 | politics and diplomacy, Simón Bolívar |
| National Library of Wales | Aberystwyth | 1907 | publications of overseas Welsh settlements |
| Royal Library | The Hague | 1798 | Hugo Grotius, Constantijn Huygens |